#手帐[超话]##和纸胶带##手帐拼贴##给你看看我的手帐吧##yr原创设计#
“She saw the world not always as it was,
with just a little bit of magic.”
YR原创设计 三周年庆
seventh：Cinderella‘s Dream
1️⃣设计主题：南瓜马车和鲜花、香薰、姜饼人的元素结合
2️⃣设计灵感：灵感来源于灰姑娘参加舞会时坐的南瓜马车
3️⃣使用思路：本条胶带以南瓜马车为主体，结合了姜饼人鲜花香薰等元素，充满了浓浓的圣诞气息，尺寸为7X126cm的超长循环，色彩清新淡雅，设计风格和脑洞独特。可以适应清新风格和圣诞气息的拼贴～
“She saw the world not always as it was,
with just a little bit of magic.”
YR原创设计 三周年庆
seventh：Cinderella‘s Dream
1️⃣设计主题：南瓜马车和鲜花、香薰、姜饼人的元素结合
2️⃣设计灵感：灵感来源于灰姑娘参加舞会时坐的南瓜马车
3️⃣使用思路：本条胶带以南瓜马车为主体，结合了姜饼人鲜花香薰等元素，充满了浓浓的圣诞气息，尺寸为7X126cm的超长循环，色彩清新淡雅，设计风格和脑洞独特。可以适应清新风格和圣诞气息的拼贴～
#SYNFACTS# Carbonylative Suzuki–Miyaura and Sonogashira Coupling Reactions with CO2 as a C1 Source https://t.cn/A6opSQSj
Comment
The cobalt sites of (Cu1Pd2)1.3@PCN-222(Co) catalyze the photoreduction of CO2 under visible-light irradiation to give CO, which serves as a C1 source. Under an argon atmosphere, the Suzuki–Miyaura coupling reaction of iodobenzene and phenylboronic acid gave biphenyl. In the reaction of iodobenzene with phenylboronic acid and CO2, the catalyst was recovered and reused four times without significant loss of its catalytic activity.
Comment
The cobalt sites of (Cu1Pd2)1.3@PCN-222(Co) catalyze the photoreduction of CO2 under visible-light irradiation to give CO, which serves as a C1 source. Under an argon atmosphere, the Suzuki–Miyaura coupling reaction of iodobenzene and phenylboronic acid gave biphenyl. In the reaction of iodobenzene with phenylboronic acid and CO2, the catalyst was recovered and reused four times without significant loss of its catalytic activity.
#SynOpen# A Homocoupling Approach to the Key Dione of CyMe4-BTPhen – Vital Ligands for Nuclear Clean-Up by the SANEX Process https://t.cn/A6opS9XZ
CyMe4-BTPhen and CyMe4-BTBP are the principal ligand systems used in Europe for the separation of actinides from lanthanides as a part of the SANEX process for nuclear recycling and reprocessing. We present a new approach to the synthesis of the CyMe4 fragment beginning from readily available hydroxypivalic acid. It features a cobalt-catalysed homocoupling of a neopentyl bromide to provide the key bisester precursor, thereby avoiding the requirement for technically challenging low-temperature LDA-mediated aldol chemistries.
CyMe4-BTPhen and CyMe4-BTBP are the principal ligand systems used in Europe for the separation of actinides from lanthanides as a part of the SANEX process for nuclear recycling and reprocessing. We present a new approach to the synthesis of the CyMe4 fragment beginning from readily available hydroxypivalic acid. It features a cobalt-catalysed homocoupling of a neopentyl bromide to provide the key bisester precursor, thereby avoiding the requirement for technically challenging low-temperature LDA-mediated aldol chemistries.
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